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• W58741943 abstract "The density of the system KF–K 2 TaF 7 –Ta 2 O 5 was measured by the Archimedean method and the surface tension by the maximum bubble pressure method in the composition range up to 20 mol% Ta 2 O 5 . The density in the system KF–K 2 TaF 7 –Ta 2 O 5 increases from KF through K 2 TaF 7 to Ta 2 O 5 and the surface tension increases from K 2 TaF 7 through KF to Ta 2 O 5 . Based on the measured density values, the molar volumes of the binary and ternary melts at 860 °C, 900 °C and 950 °C were calculated as well as the partial molar volumes of particular components in different binaries. The small negative deviation from ideal behaviour in the binary system KF–K 2 TaF 7 was identified by the calculation of the molar excess volume. The formation of complex anions [TaF 8 ] 3− is expected in this binary system. The surface tension decreases monotonically from KF to K 2 TaF 7 in the binary system KF–K 2 TaF 7 . In the next two binaries KF–Ta 2 O 5 and K 2 TaF 7 –Ta 2 O 5 decrease of the surface tension was observed with the initial addition of Ta 2 O 5 followed by the increase of the surface tension by further addition of Ta 2 O 5 . Based on measured data it was concluded that in binaries KF–Ta 2 O 5 and K 2 TaF 7 –Ta 2 O 5 the surface active component is Ta 2 O 5 and in the binary KF–K 2 TaF 7 the surface active component is K 2 TaF 7 . Mathematical description of the concentration dependence of the molar volume and surface tension of the measured ternary system was done by the polynomial function at 860°C, 900°C, and at 950°C." @default.
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• W58741943 date "2006-08-01" @default.
• W58741943 modified "2023-09-25" @default.
• W58741943 title "Density and Surface Tension of the System KF–K2TaF7–Ta2O5" @default.
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• W58741943 doi "https://doi.org/10.1524/zpch.2006.220.9.1159" @default.
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