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- W58796640 abstract "The development of the oligomer distribution during the polymerization of 13 C enriched ethylene by soluble Ziegler catalyst systems of the type Cp 2 TiMeCl/AlMe n Cl n was followed by 13 C NMR spectroscopy. It is shown that the rate of formation of new chains can be monitored directly from the spectra. The concentrations of Ti-propyl and Ti-pentyl species during the polymerization were followed; both attain a steady state concentration. These results give a greater insight into the way that the oligomer distribution develops and into the dependence on the chain length of the first insertion steps." @default.
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- W58796640 date "1986-01-01" @default.
- W58796640 modified "2023-10-01" @default.
- W58796640 title "Molecular Behaviour of Soluble Catalysts for Olefin Polymerization Part I: Ethylene insertion with soluble Ziegler Catalysts" @default.
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- W58796640 doi "https://doi.org/10.1016/s0167-2991(09)60328-1" @default.
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