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- W588331211 abstract "This chapter presents the electron microscopy and electron diffraction analysis of natural cellulose. Electron microscopy and electron diffraction analysis, together with hydrolysis and paper partition chromatography, have shown that cellulose microfibrils consist of a central crystalline core, occasionally interrupted, in which the linear chain molecules consist exclusively of glucose residues. In most celluloses, these are surrounded by a layer, separable only with difficulty, in which chains containing sugar residues other than glucose residues are admixed. These other sugars are mostly xylose and mannose. Over about 25 % of the microfibrillar surface, the xylose or mannose units are so abundant and so regularly spaced as to take up Cu++ into a regular two-dimensional lattice giving a recognizable electron diffraction diagram. By far, the most perfect microfibrils of pure cellulose occur in some seaweeds. Equally, the walls of other seaweeds contain only microfibrils in which the building units are xylose residues; still other seaweeds, in which the crystalline material is mannan, appear not to form true microfibrils. The structure of the microfibrils and their organization in the wall suggest that they are produced by end synthesis by a mechanism that, in the plants studied, can orient them in a limited number of directions. The orienting mechanism is a function of the surface organization of the cytoplasm." @default.
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- W588331211 date "1962-01-01" @default.
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- W588331211 title "THE ELECTRON MICROSCOPY AND ELECTRON DIFFRACTION ANALYSIS OF NATURAL CELLULOSE" @default.
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- W588331211 doi "https://doi.org/10.1016/b978-1-4832-3079-5.50021-7" @default.
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