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- W589617809 abstract "Abstract Transformations of lower aliphatic nitrocompounds in supercritical isopropanol in a flow reactor in the presence of alumina were studied. In experiments with 1-nitropropane, the dominant process was the never-before-observed formation of an amine with a shorter by one carbon atom chain as compared to the initial nitroalkane. The reaction mechanism was suggested which adequately explained the formation of all detected products. The reactions of nitroethane and nitromethane partly proceeded by a new transformation route yielding isopropylamine." @default.
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- W589617809 date "2015-08-01" @default.
- W589617809 modified "2023-09-23" @default.
- W589617809 title "Unique shortening of carbon chain during reduction of aliphatic nitro compounds to amines in the presence of supercritical isopropanol on alumina" @default.
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- W589617809 doi "https://doi.org/10.1016/j.supflu.2015.04.029" @default.
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