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- W59318311 abstract "We discuss self-assembling structures and phase transition of polymer systems under a Couette type shear-flow. Ternary systems with polymer A + polymer B + solvent, forming a semidilute solution of A/B mixtures, exhibit strongly elongated self-assembling structures under the shear and are brought back into single-phase state at a higher shear rate. The drop of critical temperature with shear is much larger than that for the critical mixture of simple liquids by three-to-four orders of magnitude. The ternary systems with off-critical compositions exhibit ellipsoidal droplets with an extremely narrow size distribution at a low shear rate and a shear-induced cluster-to-percolation transition at a higher shear-rate. Finally a trend completely opposite to the shear-induced homogenization will be presented for a binary mixture of polymer A + solvent." @default.
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- W59318311 date "1990-01-01" @default.
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- W59318311 title "Phase Transition and Self-Assembling Structures of Polymer Mixtures under Shear Flow" @default.
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- W59318311 doi "https://doi.org/10.1007/978-3-642-76008-2_17" @default.
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