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- W5963326 abstract "A number of [8]annulene actinide and lanthanide compounds are now known at oxidation levels of the central metal of +2, +3, and +4. Several structures have been established for these compounds. The [8]annulene ring is generally present as a planar octagonal ring of carbons with the metal centrally located. Many structures are those of sandwich compounds with the metal located between parallel rings. The original system, uranocene, is the most stable and the most thoroughly studied of these compounds. Only limited chemistry has been explored so far with these systems; in the sandwich compounds the large rings hinder coordination at the central metal. Uranocene is paramagnetic and shows a wide range of 1H chemical shifts that have been particularly useful in studies of structure and electronic structure. Especially valuable are derived barriers for a number of dynamic processes. These energies provide significant new information concerning intramolecular interactions." @default.
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- W5963326 date "1985-01-01" @default.
- W5963326 modified "2023-10-03" @default.
- W5963326 title "[8]Annulene Derivatives of Actinides and Lanthanides" @default.
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- W5963326 doi "https://doi.org/10.1007/978-94-009-5406-9_3" @default.
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