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• W59891619 abstract "The authors have made an x-ray structural investigation of single crystals of the ferroelectric modification of NaTh 2 (PO 4 ) 3 (Mo Kα radiation, R = 4.89%, R w = 5.02% for 1295 reflections). The parameters of the monoclinic lattice are: a = 17.157, b = 6.809, c = 8.133 A, β = 100.96°, Z = 4, space group Cc. The authors have established the splitting of the Na positions (populations 0.74 and 0.23, Na-Na distance 1.88 A) with formation of a system of uncompensated statistical Na dipoles, determining the dipole ordering of the ferroelectric type. The authors suggest a model of the ferroelectric-ionic conductor phase transition on the basis of differential scanning calorimetry data and previously published information on the temperature dependences of the dielectric permittivity and the second-harmonic signal" @default.
• W59891619 created "2016-06-24" @default.
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• W59891619 date "1992-01-01" @default.
• W59891619 modified "2023-09-27" @default.
• W59891619 title "CRYSTALLINE-STRUCTURE AND PHASE-TRANSITION IN NATH2(PO4)3" @default.
• W59891619 hasPublicationYear "1992" @default.
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