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- W6019775 abstract "A survey of the literature suggests that a thia-atom is more or less readily extruded from a heterocycle if the ring contraction involved leads to an aromatic structure. This theme is illustrated by examples of sulfur extrusion from six- and seven-membered cyclic sulfides, sulfoxides or sulfones, and more particularly by the synthesis of phenanthridines from dibenzothiazepines. No single mechanism is likely to account for the variety of formally similar reactions but attention is directed to episulfides as possible intermediates in certain extrusions." @default.
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- W6019775 date "1961-01-01" @default.
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- W6019775 title "THE EXTRUSION OF SULFUR" @default.
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