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- W602695251 startingPage "499" @default.
- W602695251 abstract "水素化物生成/原子吸光法でテルルを定量するとき,テルル(VI)は検出されずテルル(IV)のみが検出されるので,測定溶液はテルル(IV)としなければならない.したがって,酸化分解処理した毛髪試料溶液中の全テルルすなわちテルル(VI)を還元するため,6mol/l塩酸溶液で煮沸処理しテルル(IV)とした.本法を毛髪試料に適用する場合,試料中のppmレベルの銅がテルルの測定を妨害するので,鉄共沈により銅を分離した.すなわち,毛髪試料を硝酸-過塩素酸により分解し,塩酸による還元処理後,アンモニア水でpH9とし,生成した水和酸化鉄にテルル(IV)を共沈させた.遠心分離により得た沈殿部を塩酸で溶解し,これを測定溶液とした.本法により,成人毛髪中のテルルを分析した結果,2~7ng/gであった." @default.
- W602695251 created "2016-06-24" @default.
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- W602695251 date "1999-01-01" @default.
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- W602695251 title "Determination of tellurium in human hair by hydride generation-AAS following the iron(III) coprecipitation method." @default.
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- W602695251 doi "https://doi.org/10.2116/bunsekikagaku.48.499" @default.
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