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• W60412652 abstract "NMR spectroscopy is an important analytical method that is extensively used to study the structure and properties of macromolecules. NMR methods developed rapidly after these initial observations, both for polymers in solution and in the solid state. Solution NMR has emerged as one of the premier methods for polymer characterization because of its high resolution and sensitivity. It is observed in the early studies that the chemical shifts are sensitive to polymer microstructure, including polymer stereochemistry, regioisomerism, and the presence of branches and defects. This chapter gives an overview of the applications of NMR for the determination of polymer structure and dynamics. NMR is a complex method that is being used for a wide variety of applications ranging from microstructural characterization to structure determination in solid polymers. On one level, these NMR methods are relatively simple and can be performed on routine instruments. On another level, there is a very active research effort to develop new methods to probe the structure and dynamics of polymers at an ever more detailed level. The new research efforts are aided by developments in magnets, probes, spectrometers, and pulse sequences. This advance is driven in part by the desire to understand the molecular level structure and dynamics of polymers, and how these properties relate to the observed macroscopic properties." @default.
• W60412652 created "2016-06-24" @default.
• W60412652 creator A5084711558 @default.
• W60412652 date "2000-01-01" @default.
• W60412652 modified "2023-10-18" @default.
• W60412652 title "NMR CHARACTERIZATION OF POLYMERS" @default.
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• W60412652 doi "https://doi.org/10.1016/b978-008043417-9/50039-8" @default.
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