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• W604359024 abstract "Phase equilibrium relationships in igneous systems can be estimated using empirical mathematical models based onmulti-component regular solution formulae. Although these provide useable results within the fitted region, they cangive very misleading values outside the compositional range of curve fitting. Moreover, they usually give poor estimatesof the well-characterized melting relations of simple systems and do not relate to the large body of thermodynamicactivity data available in the metallurgical literature, nor to spectroscopic, diffraction or computational modelsof silicate melt properties. The aim of this paper is to extend previous acid-base models of silicate melts and touse a quasi-chemical model to calculate the activities of quasi-chemical silicate mixing units, or structons, from combinationsof the oxo-species used in quasi-chemical and polymer models to calculate oxide activities in metallurgy." @default.
• W604359024 created "2016-06-24" @default.
• W604359024 creator A5071546731 @default.
• W604359024 date "2009-12-18" @default.
• W604359024 modified "2023-09-28" @default.
• W604359024 title "Acid-base properties and structons: towards a structural model for predicting the thermodynamic properties of silicate melts" @default.
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• W604359024 doi "https://doi.org/10.4401/ag-3219" @default.
• W604359024 hasPublicationYear "2009" @default.
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