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• W60612658 abstract "With the exception of the C atoms of two of the methyl groups of the tert-butyl substituent, all of the non-H atoms of the title compound, C(12)H(14)ClN(3)O(3)S, lie on a mirror plane. The 2-chloro-5-nitro-phenyl and 2,2-dimethyl-propionyl substituents are, respectively, cis and trans relative to the thio-carbonyl S atom across the two C-N bonds. Intra-molecular N-H⋯O and C-H⋯S hydrogen bonds form S(6) ring motifs, also in the mirror plane. Despite the presence of two N-H subsituents, no inter-molecular hydrogen bonds are observed in the crystal structure. Weak π-π contacts [centroid-centroid distances of 4.2903 (17) Å] involving adjacent aromatic rings link the mol-ecules in a head-to-tail fashion above and below the mol-ecular plane." @default.
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• W60612658 date "2009-07-01" @default.
• W60612658 modified "2023-09-27" @default.
• W60612658 title "1-(2-Chloro-5-nitrophenyl)-3-(2,2-dimethylpropionyl)thiourea" @default.
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• W60612658 doi "https://doi.org/10.1107/s1600536809024672" @default.
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