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- W607673676 abstract "Titanium-aluminides (containing (alpha)2-Ti3Al and gamma-TiAl intermetallic phases) have received continued research focus due to their potential as low-density materials for structural applications at intermediate temperatures. However their application above about 850C is hindered by poor oxidation resistance, characterized by the formation of a non-protective TiO2+Al2O3 scale and an oxygen-enriched subsurface zone. Consistent with this are measured titanium and aluminum activities in oxygen-free titanium-aluminides, which indicate Al2O3 is only stable for aluminum concentrations greater then 54 atom percent at 1373 K. However, the inability to form a protective Al2O3 scale is in apparent conflict with phase diagram studies, as experimental isothermal sections of the Ti-Al-O system show gamma-TiAl + alpha2-Ti3Al structures are in equilibrium only with Al2O3. The apparent resolution to this conflict lies in the inclusion of oxygen effects in the thermodynamic measurements" @default.
- W607673676 created "2016-06-24" @default.
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- W607673676 date "2003-05-19" @default.
- W607673676 modified "2023-09-27" @default.
- W607673676 title "Component Activity Measurements in the Ti-Al-O System by Knudsen Cell Mass Spectrometry" @default.
- W607673676 hasPublicationYear "2003" @default.
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