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- W608946671 abstract "This chapter provides a basic review of the environmental fate of the two most common munition constituents used by the DoD, TNT and RDX. Here is reviewed the basic scientific literature of nitroaromatic and tirazine sorption, with specific data that is available for TNT and RDX. In general, the behavior of these munition constituents (MC) in soils and sediments is generally well described by the available information for nitroaromatic and triazine compounds, with notable differences attributed to the ready reduction of MC nitro groups to amine derivatives. In general, the environmental fate of TNT is much better described in the scientific literature, emphasizing a remaining need for more research elucidating the behavior of RDX in soil and sediments. Here, we summarize trends in reported partitioning coefficients describing sorption of MC with soil/sediment cation exchange capacity (CEC), extractable Fe, and exchangeable Ca. New concepts in terms of fugacity-based quantity-intensity theory are introduced for more detailed descriptions of sorption behavior. Also, we expand on classical considerations of soil biological degradation potentials to include agricultural concepts of soil tilth for predicting the long-term fate of MC in soil." @default.
- W608946671 created "2016-06-24" @default.
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- W608946671 date "2011-01-01" @default.
- W608946671 modified "2023-10-14" @default.
- W608946671 title "Environmental Chemistry of Explosives and Propellant Compounds in Soils and Marine Systems: Distributed Source Characterization and Remedial Technologies" @default.
- W608946671 doi "https://doi.org/10.1021/bk-2011-1069" @default.
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