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- W61267384 abstract "Enhancement of electronic chemiluminescence by the introduction of dimers or metastable states of main-group metals in molecular beam reactions with halogen and oxygen containing molecules is surveyed. Reactions of metals in groups 2, 14, and 15 are considered. The importance of symmetry and collisional lifetime in controlling the reaction pathway and energy disposal in products is discussed. New experimental results are reported on alkaline earth atom reactions with hydrogen peroxide in which metastable atoms form exclusively metal hydroxide products, unlike ground state atoms which form metal monoxide and hydroxide products. Chemiluminescent mechanisms involving reactions of bismuth and antimony dimers with fluorine are also described." @default.
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- W61267384 date "1992-01-01" @default.
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- W61267384 title "Effects of Electronic Excitation and Dimerization of Metals on Product State Distributions" @default.
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