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- W61363776 abstract "Reduction of 4-trichloromethy1-4-methyl-2, 5-cyclohexadien-1-one (1) and 4-dichloromethy1-4methy1-2, 5-cyclohexadien-1-one (7) by the use of bakers' yeast was studied. Reduction of 1 proceeded at the C = 0 bonds electiveltyo h ivec -4- andt -4-trichloromethy1-4-methyl-2, 5-cyclohexadien-r-1-ol (c- 4: t-4=42: 58). On the other hand, 7 was reduced to c-4-and t-4-dichloromethyl-4-methyl-r1-cyclohexanol (c- 4: t- 4 =72: 28) through cyclohexen-1-one (8) and cyclohexanone (9). The reduction of 4-trichloromethyl-4-methylcyclohexanone (4) proceeded more stereoselectively to afford c-4-and t-4-trichloromethyl-4-methyl-r-1-cyclohexanol (c- 4: t- 4 =97: 3)." @default.
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- W61363776 date "1994-01-01" @default.
- W61363776 modified "2023-10-18" @default.
- W61363776 title "Reduction of 4-Trichloromethyl-4-methyl- and 4-Dichloromethyl-4-methyl-2,5-cyclohexadien-1-one with Bakers' Yeast." @default.
- W61363776 doi "https://doi.org/10.1246/nikkashi.1994.945" @default.
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