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- W613920513 abstract "プロトン付加陽イオンから成るイオン液体(IL)を用いて塩酸溶液からの金(III)の抽出挙動を調べた.用いたプロトン性ILは,1-ブチルイミダゾリウム([BImH]+),1-ブチルピロリジニウム([BPyrH]+),トリオクチルアンモニウム([TOAH]+)のビス(トリフルオロメタンスルホニル)アミド([NTf2]-)塩である.5 × 10-7~6 × 10-4 mol dm-3の金(III)を含む0.1~4 mol dm-3塩酸から抽出を行ったとき,抽出率は塩酸濃度が低いほど,また,金濃度が高いほど上昇した.ILの抽出能力は[TOAH][NTf2]>[BImH][NTf2]>[BPyrH][NTf2]の順であり,[TOAH][NTf2]を用いた場合は0.1 mol dm-3塩酸から1/10容のIL相に金(III)をほぼ定量的に抽出することができた.抽出平衡の解析から,抽出化学種は無電荷の[AuCl3]及び[Au2Cl6]であることが示唆された." @default.
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- W613920513 date "2014-01-01" @default.
- W613920513 modified "2023-09-23" @default.
- W613920513 title "Extraction Behavior of Gold(III) from Hydrochloric Acid Solutions by Protic Ionic Liquids" @default.
- W613920513 doi "https://doi.org/10.2116/bunsekikagaku.63.563" @default.
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