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- W613937273 abstract "Abstract A new pentadentate chelate-bridging ligand possessing an inner N 2 O 3 coordination site with one amide, one imine, and two phenoxo functions, 2-hydroxy-N-(2-(((3-hydroxynaphthalen-2-yl)methylene)amino)ethyl)benzamide (H 3 L), was synthesised. Reaction it with Mn(OAc) 2 ·4H 2 O yielded a novel zigzag penta-coordinated Mn(III) coordination polymer, [MnL] n , due to the bridging ability of the amide function. The crystal structure of [MnL] n has been determined at 293 K which crystallizes in the monoclinic space group P2 1 /c (No. 14): a = 16.0601(12) A, b = 8.4048(6) A, c = 12.7168(10) A, β = 112.395(9), V = 1606.0(2) A 3 , Z = 4. The experimental magnetic susceptibilities indicates the Mn(III) coordination polymer exhibits dominant antiferromagnetic interactions between the manganese centers through the amido bridge, and spin canting is observed with a ferromagnetic transition occurring at 8.5 K." @default.
- W613937273 created "2016-06-24" @default.
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- W613937273 date "2015-08-01" @default.
- W613937273 modified "2023-09-26" @default.
- W613937273 title "Synthesis, structure and magnetic properties of a new one dimensional manganese coordination polymer constructed by a new asymmetrical ligand" @default.
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- W613937273 doi "https://doi.org/10.1016/j.ica.2015.05.026" @default.
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