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- W615153468 abstract "I. Thermodynamics and Magnetism of Cu2OCl2 II. Repairs to Microcalorimeter Thomas Parry Department of Chemistry and Biochemistry Master of Science Adiabatic calorimetry provides accurate and precise specific heat (Cp) data. From this data, thermodynamic functions may be calculated. Cu2OCl2, melanothallite, became of interest as part of a study of a particular thermochemical cycle. The experimental specific heat data and the calculated thermodynamic functions are reported here. Free energies of formation, calculated from the thermodynamic functions, suggest the particular cycle of interest with this compound as an intermediate is not feasible; uncertainty as to the accuracy of CuO and CuCl2 data used in the calculations indicate further study may be necessary. Upon collection of the specific heat data, an antiferromagnetic transition was observed at 70 K; this led to examination of the magnetic heat capacity and entropy of the transition in melanothallite. The entropy of the transition was estimated to be 18.1 % and 7.5 % of 2Rln2 by two" @default.
- W615153468 created "2016-06-24" @default.
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- W615153468 date "2008-01-01" @default.
- W615153468 modified "2023-09-26" @default.
- W615153468 title "I. Thermodynamics and Magnetism of Cu2OCl2 II. Repairs to Microcalorimeter the 2s are subscripts, and the second 2 is preceded by a lower case L, not a one" @default.
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