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- W61548439 abstract "Early studies of the kinetics of nitration led to a rather complicated dependence of rate on concentrations and other conditions. It was found in these studies, however, that the behavior was much simpler when concentrated sulfuric acid was used as solvent. The nitration of nitrobenzene, for example, was first-order in nitric acid and first-order in nitrobenzene. In organic solvents—such as dioxane—with an excess of nitric acid, the nitration was zero-order in the case of benzene, toluene, and ethylbenzene, and the rates were the same under the same conditions for all three compounds. For aromatic compounds of lower reactivity such as chlorobenzene, the rate depended on the concentration of the chlorobenzene, the order being between zero and one. With the still less reactive compound nitrobenzene, the order was unity with respect to the nitrobenzene concentration. The polymerization of isobutene may be taken as an example of an ionic mechanism." @default.
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- W61548439 date "1963-01-01" @default.
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- W61548439 title "Some Reaction Mechanisms in Solution" @default.
- W61548439 doi "https://doi.org/10.1016/b978-0-08-009836-4.50006-1" @default.
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