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- W616646142 startingPage "188" @default.
- W616646142 abstract "種々のコバルト (III) アンミン錯塩-アルカリルミノール系の化学発光を光電測光により検した結果, [Co(NH3)4Cl2(1)(6)]Cl, [Co(NH3)4Cl⋅(OH2)]Cl2, [Co(NH3)4(OH2)2]Cl3, [Co(NH3)4(OH)⋅(OH2)]Cl2, [Co(NH3)5Cl]Cl2, [Co(NH3)5(OH)]Cl2, [Co(NH3)4CO3]Cl, Na3[Co(NO2)6]の8種が顕著な発光 (過酸化水素等の酸化剤なし) を与えることを見出した。この中の前4者, すなわち, 置換し易い水分子または塩素イオンを配位する錯塩を加えた場合の発光はとくに顕著である。また[Co(NH3)4(OH2)2]Cl3を用いた場合, 加える錯塩水溶液の調製後の放置時間を長くするほど発光初期強度は大となる等の事実より, この系の化学発光はコバルト (III) アンミン錯塩の配位子置換を起し易い水分子と共存する酸素とが発光機構にあずかるものと考えられる。" @default.
- W616646142 created "2016-06-24" @default.
- W616646142 creator A5073725992 @default.
- W616646142 date "1958-01-01" @default.
- W616646142 modified "2023-09-25" @default.
- W616646142 title "Chemiluminescence of Luminol in the Presence of Metallic Complexes. II. Catalytic Activity of Cobalt (III) Ammine Complexes in the Chemilumi nescence of Alkali-Luminolate (without Hydrogen Peroxide)." @default.
- W616646142 doi "https://doi.org/10.1246/nikkashi1948.79.188" @default.
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