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- W618184450 abstract "A NEW HYPOTHESIS IS PROPOSED TO EXPLAIN CLAY SWELLING WHICH TAKES INTO ACCOUNT THE OBSERVED RELATION BETWEEN FREE SWELLING AND B-DIMENSION. THIS HYPOTHESIS IS ESSENTIALLY AS FOLLOWS. THE STRUCTURES OF INTERLAYER WATER AND MONTMORILLONITE CONFORM TO EACH OTHER, I.E., EPITAXY OCCURS, BECAUSE OF THE HYDROGEN BONDING THAT EXISTS BETWEEN THEM. AS THE INTERLAYER WATER INCREASES IN THICKNESS, ITS STRUCTURE TENDS TO ASSUME A PREFERRED CONFIGURATION AND THE MONTMORILLONITE STRUCTURE ADJUSTS ACCORDINGLY. THIS ADJUSTMENT CONTINUES UNTIL THE WATER ACHIEVES ITS PREFERRED CONFIGURATION. OR, ALTERNATIVELY, THE MONTMORILLONITE STRUCTURE RELAXES AS STRESSES ACTING ON IT ARE RELIVED BY THE INCLUSION OF WATER, AND THE WATER STRUCTURE CHANGES CONFOMABLY. THIS RELAXATION CONTINUES UNTIL THE WATER STRUCTURE RESISTS FURTHER STRAIN. IN EITHER EVENT, THE B-DIMENSION INCREASES AS THE INTERLAYER WATER INCREASES IN THICKNESS AND ITS FINAL VALUE IS GOVERNED BY THE WATER. HENCE, ITS IS THE SAME FOR EVERY MAXIMALLY SWOLLEN MONTMORILLONITE. THE MUTUAL ADJUSTMENT OF THE MONTMORILLONITE AND WATER STRUCTURES, WHICH ACCOMPANIES THE ABSORPTION OF WATER, NECESSARILY CAUSES A CHANGE IN THEIR STRUCTURAL ENERGIES. THE NET CHANGE IN ENERGY IS PRESUMED TO BE NEGATIVE. THEREFORE, THE WATER IS ABSORBED SPONTANEOUSLY. WATER ABSORPTION (SWELLING) STOP WHEN NO FURTHER STRUCTURAL ADJUSTMENTS OCCUR, I.E., WHEN THE B-DIMENSION REACHES ITS FINAL VALUE. THUS, SWELLING IS RELATED TO THE CHANGE IN B-DIMENSION." @default.
- W618184450 created "2016-06-24" @default.
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- W618184450 date "1973-05-01" @default.
- W618184450 modified "2023-09-27" @default.
- W618184450 title "FUNDAMENTAL MECHANISMS INVOLVED IN EXPANSION OF CLAYS AS PARTICULARY RELATED TO CLAY MINERALOGY" @default.
- W618184450 hasPublicationYear "1973" @default.
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