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- W62191607 abstract "The continuum absorption by laboratory samples of pure H 2 O and of H 2 0 + N 2 throughout the infrared and millimeter regions has been studied. The samples cover a wide range of pressures and temperatures from 296 K to 428 K. Measurements have been made in the well-known 4 μm and 8 to 12 μm windows as well as in many very narrow “windows” between rotation and vibration-rotation lines. An empirical continuum has been derived for each of several spectral regions to account for the “excess” absorption observed for pure H 2 O over that calculated on the basis of known line strengths and widths and simple line shapes. The results indicate that much of the continuum absorption previously attributed to dimers, or clusters of H 2 O molecules, is due to the extreme wings of self-broadened H 2 O lines. If this is true, the lines must have three important characteristics that are not predicted by simple line-shape theories : (1) self-broadened lines absorb much more in the extreme wings than do N 2 -broadened lines of the same intensity and width; (2) the absorption in the extreme wings decreases with increasing temperature faster than is predicted by simple theory; (3) characteristic (2) is more pronounced for self-broadened lines than for N 2 broadened lines." @default.
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- W62191607 date "1980-01-01" @default.
- W62191607 modified "2023-10-13" @default.
- W62191607 title "CONTINUUM ABSORPTION BY H2O VAPOR IN THE INFRARED AND MILLIMETER REGIONS" @default.
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- W62191607 doi "https://doi.org/10.1016/b978-0-12-208440-9.50008-9" @default.
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