FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W623724211> ?p ?o ?g. }

• W623724211 abstract "A new titanium (IV) butoxide-cyanopropyltriethoxysilane (Ti-CNPrTEOS) hybrid material was successfully synthesized as sorbent for the extraction of polar aromatic amines. The sorbent was synthesized by hydrolysis and condensation of titanium (IV) butoxide and cyanopropyltriethoxysilane with the presence of hydrochloric acid as catalyst via sol-gel method. Under the optimum synthesis conditions (tetrahydrofuran as solvent, 1.2 M of hydrochloric acid catalyst, 4 mol of water content with ratio of titanium (IV) butoxide and cyanopropylteriethoxysilane of 1:1 and aging temperature of 60°C), the sorbents were characterized by Fourier Transform-Infrared, Field-Emission Scanning Electron Microscopy-Energy, CHN elemental analysis, Brunauer–Emmett–Teller (BET) desorption and thermogravimetric analysis. A solid phase extraction (SPE) method has been developed using Ti-CNPrTEOS sorbent for the determination of aromatic amines and optimum experimental conditions were sample at pH 7, dichloromethane as conditioning solvent, 10 mL sample loading volume, 5 mL of acetonitrile as the eluting solvent. The limit of detection (LOD) and limit of quantification (LOQ) using Ti-CNPrTEOS SPE sorbent (0.01-0.20; 0.03-0.61 µgL-1) were absolutely lower compared with those achieved using silica-cyanopropyl (Si-CN) SPE sorbent (0.23-1.47; 0.75-4.91 µgL-1) and C18 SPE sorbent (0.36-0.98; 1.54-2.56 µgL-1). The recoveries and repeatability obtained from water samples using the sol–gel Ti-CNPrTEOS SPE sorbent were 57–99% and RSDs 1–4%, n=5. The lowest recovery of non-polar diethylaniline, DEA (57%) indicated that the sorbent was very selective towards the extraction of polar aromatic amines. Ti-CNPrTEOS sorbent was also successfully applied as sorbent for solid phase membrane tip extraction (SPMTE). Under the optimum extraction conditions; 15 mL of sample at pH 7, acetonitrile as conditioning and desorption organic solvent, extraction time of 15 min and desorption time of 15 min, the method showed good linearity with acceptable reproducibility (RSD 2.5 – 3.6%, n = 5) and LOD and LOQ for Ti-CNPrTEOS SPMTE (0.13 – 6.23 ngL-1; 0.53 – 5.67 ngL-1) were lower with those achieved by C18-SPE (0.36-0.98 gL-1; 1.54-2.56 gL-1). The application of the Ti-CNPrTEOS SPMTE sorbent was successfully carried out by analysis of aromatic amines in river water sample with the recovery between 49–99%. The lowest recovery of non-polar DEA (49%) indicated that the sorbent was very selective towards the extraction of polar aromatic amines. The newly developed method using Ti-CNPrTEOS sorbent was proven as a simple, rapid, cheap and solvent efficient extraction technique." @default.
• W623724211 created "2016-06-24" @default.
• W623724211 creator A5024885795 @default.
• W623724211 date "2014-01-01" @default.
• W623724211 modified "2023-09-27" @default.
• W623724211 title "Application of newly synthesized titanium (iv) butoxide-cyanopropyltriethoxysilane sorbent for the extraction of aromatic amines in water samples / Mazidatulakmam binti Miskam" @default.
• W623724211 hasPublicationYear "2014" @default.
• W623724211 type Work @default.
• W623724211 sameAs 623724211 @default.
• W623724211 citedByCount "0" @default.
• W623724211 crossrefType "dissertation" @default.
• W623724211 hasAuthorship W623724211A5024885795 @default.
• W623724211 hasConcept C119128265 @default.
• W623724211 hasConcept C13965031 @default.
• W623724211 hasConcept C150394285 @default.
• W623724211 hasConcept C178790620 @default.
• W623724211 hasConcept C179104552 @default.
• W623724211 hasConcept C185592680 @default.
• W623724211 hasConcept C192562407 @default.
• W623724211 hasConcept C2777436746 @default.
• W623724211 hasConcept C2777899863 @default.
• W623724211 hasConcept C2780471494 @default.
• W623724211 hasConcept C43617362 @default.
• W623724211 hasConcept C4725764 @default.
• W623724211 hasConcept C506065880 @default.
• W623724211 hasConcept C81426234 @default.
• W623724211 hasConceptScore W623724211C119128265 @default.
• W623724211 hasConceptScore W623724211C13965031 @default.
• W623724211 hasConceptScore W623724211C150394285 @default.
• W623724211 hasConceptScore W623724211C178790620 @default.
• W623724211 hasConceptScore W623724211C179104552 @default.
• W623724211 hasConceptScore W623724211C185592680 @default.
• W623724211 hasConceptScore W623724211C192562407 @default.
• W623724211 hasConceptScore W623724211C2777436746 @default.
• W623724211 hasConceptScore W623724211C2777899863 @default.
• W623724211 hasConceptScore W623724211C2780471494 @default.
• W623724211 hasConceptScore W623724211C43617362 @default.
• W623724211 hasConceptScore W623724211C4725764 @default.
• W623724211 hasConceptScore W623724211C506065880 @default.
• W623724211 hasConceptScore W623724211C81426234 @default.
• W623724211 hasLocation W6237242111 @default.
• W623724211 hasOpenAccess W623724211 @default.
• W623724211 hasPrimaryLocation W6237242111 @default.
• W623724211 hasRelatedWork W1964403523 @default.
• W623724211 hasRelatedWork W1965188989 @default.
• W623724211 hasRelatedWork W1988328931 @default.
• W623724211 hasRelatedWork W2001504904 @default.
• W623724211 hasRelatedWork W2008162807 @default.
• W623724211 hasRelatedWork W2010203090 @default.
• W623724211 hasRelatedWork W2037900492 @default.
• W623724211 hasRelatedWork W2058235390 @default.
• W623724211 hasRelatedWork W2107700853 @default.
• W623724211 hasRelatedWork W2158015693 @default.
• W623724211 hasRelatedWork W2288290041 @default.
• W623724211 hasRelatedWork W2316166927 @default.
• W623724211 hasRelatedWork W2384213244 @default.
• W623724211 hasRelatedWork W2460906498 @default.
• W623724211 hasRelatedWork W3040321681 @default.
• W623724211 hasRelatedWork W3082063533 @default.
• W623724211 hasRelatedWork W3097417313 @default.
• W623724211 hasRelatedWork W3172608789 @default.
• W623724211 hasRelatedWork W3208145725 @default.
• W623724211 hasRelatedWork W2911829942 @default.
• W623724211 isParatext "false" @default.
• W623724211 isRetracted "false" @default.
• W623724211 magId "623724211" @default.
• W623724211 workType "dissertation" @default.