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- W624263756 abstract "The rates of complexation of the 18-C-6 (1,4,7,10,13,16-hexaoxacyclooctadecane) with in methanol solution have been determined at 25 by a pressure-jump technique. The Eigen Winkler mechanism has been applied to interprete the kinetic data. The results suggest that the rate determining step of the complexation in methanol is the rearrangement of the ligand in the outer sphere ion-dipole pair to form a stable encapsulated complex of the metal ion by the crown ether." @default.
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- W624263756 date "1989-01-01" @default.
- W624263756 modified "2023-09-24" @default.
- W624263756 title "Kinetics of Complexation of Alkali Earth Metal Ions with 18-Crown-6-Ether in Methanol" @default.
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