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- W625416498 abstract "[35](1,2,3,4,5)Cyclophane 3 was synthesized by an acid-catalyzed eyclization between a pseudogeminally substituted acetyl group and a chloromethyl group of a tetra-bridged compound followed by two-step hydrogenation of the resulting penta-bridged bromo-olefin. 3 shows the strongest transannular π–π interaction among [m.n]- and multibridged benzenophanes synthesized so far. 3 is conformationally mobile at room temperature in CD2Cl2, and two conformers 3a and 3b are observed at −90 °C." @default.
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- W625416498 date "1994-04-01" @default.
- W625416498 modified "2023-10-16" @default.
- W625416498 title "Synthesis of [3<sub>5</sub>](1,2,3,4,5)Cyclophane" @default.
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- W625416498 doi "https://doi.org/10.1246/cl.1994.669" @default.
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