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- W62639136 abstract "The sulfur sensitivity of a monofunctional Pt/KL catalyst has been investigated. Sulfur, in the ppb range, introduced in the form of thiophene functions as a stiochiometric poison and lowers, thereby, the number of available Pt sites. Additionally, feed sulfur greatly accelerates Pt agglomeration. Pt/KL deactivation resulting from metal agglomeration primarily occurs by blockage of KL channels by 10–50 Å Pt and/or PtS particles. The sulfur sensitivity of the Pt/KL catalyst is highly dependent upon the molecular structure of the sulfur source. The order of sensitivity, at constant sulfur level, is thiophene ≫ 1,2-benzodiphenylene sulfide > propanethiol > sulfolane." @default.
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- W62639136 date "1993-01-01" @default.
- W62639136 modified "2023-09-26" @default.
- W62639136 title "Effect of Sulfur on the Performance of Pt/KL Hexane Aromatization Catalyst" @default.
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- W62639136 doi "https://doi.org/10.1016/s0167-2991(08)64430-4" @default.
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