FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W6267398> ?p ?o ?g. }

• W6267398 endingPage "1783" @default.
• W6267398 startingPage "1777" @default.
• W6267398 abstract "Highly water-soluble hydroxylated fullerene derivatives are being investigated for a wide range of commercial products as well as for potential cytotoxicity. However, no analytical methods are currently available for their quantification at sub-ppm concentrations in environmental matrixes. Here, we report on the development and comparison of liquid chromatography-ultraviolet/visible spectroscopy (LC-UV/vis) and liquid chromatography-mass spectrometry (LC-MS) based detection and quantification methods for commercial fullerols. We achieved good separation efficiency using an amide-type hydrophilic interaction liquid chromatography (HILIC) column (plate number >2000) under isocratic conditions with 90% acetonitrile as the mobile phase. The method detection limits (MDLs) ranged from 42.8 ng/mL (UV detection) to 0.19 pg/mL (using MS with multiple reaction monitoring, MRM). Other MS measurement modes achieved MDLs of 125 pg/mL (single quad scan, Q1) and 1.5 pg/mL (multiple ion monitoring, MI). Each detection method exhibited a good linear response over several orders of magnitude. Moreover, we tested the robustness of these methods in the presence of Suvanee River fulvic acids (SRFA) as an example of organic matter commonly found in environmental water samples. While SRFA significantly interfered with UV- and Q1-based quantifications, the interference was relatively low using MI or MRM (relative error in presence of SRFA: 8.6% and 2.5%, respectively). This first report of a robust MS-based quantification method for modified fullerenes dissolved in water suggests the feasibility of implementing MS techniques more broadly for identification and quantification of fullerols and other water-soluble fullerene derivatives in environmental samples." @default.
• W6267398 created "2016-06-24" @default.
• W6267398 creator A5025419758 @default.
• W6267398 creator A5026527210 @default.
• W6267398 creator A5052226398 @default.
• W6267398 creator A5062731220 @default.
• W6267398 creator A5065884186 @default.
• W6267398 creator A5077501113 @default.
• W6267398 date "2011-02-04" @default.
• W6267398 modified "2023-10-10" @default.
• W6267398 title "Characterization and Liquid Chromatography-MS/MS Based Quantification of Hydroxylated Fullerenes" @default.
• W6267398 cites W1964352589 @default.
• W6267398 cites W1964487259 @default.
• W6267398 cites W1971550188 @default.
• W6267398 cites W1989195046 @default.
• W6267398 cites W1997244613 @default.
• W6267398 cites W2000368651 @default.
• W6267398 cites W2003171474 @default.
• W6267398 cites W2004588569 @default.
• W6267398 cites W2006043039 @default.
• W6267398 cites W2014160153 @default.
• W6267398 cites W2020920760 @default.
• W6267398 cites W2024236165 @default.
• W6267398 cites W2026087390 @default.
• W6267398 cites W2028372958 @default.
• W6267398 cites W2029654471 @default.
• W6267398 cites W2033822300 @default.
• W6267398 cites W2039291141 @default.
• W6267398 cites W2042460638 @default.
• W6267398 cites W2044607623 @default.
• W6267398 cites W2045135154 @default.
• W6267398 cites W2045959921 @default.
• W6267398 cites W2049200141 @default.
• W6267398 cites W2051007957 @default.
• W6267398 cites W2055888815 @default.
• W6267398 cites W2057318450 @default.
• W6267398 cites W2063267873 @default.
• W6267398 cites W2063824519 @default.
• W6267398 cites W2066357786 @default.
• W6267398 cites W2066378756 @default.
• W6267398 cites W2068780396 @default.
• W6267398 cites W2069497025 @default.
• W6267398 cites W2076584552 @default.
• W6267398 cites W2078088120 @default.
• W6267398 cites W2082856847 @default.
• W6267398 cites W2088871295 @default.
• W6267398 cites W2094583480 @default.
• W6267398 cites W2111836708 @default.
• W6267398 cites W2122618654 @default.
• W6267398 cites W2148087804 @default.
• W6267398 cites W2163360515 @default.
• W6267398 cites W2473168508 @default.
• W6267398 cites W2952858532 @default.
• W6267398 cites W4235470089 @default.
• W6267398 doi "https://doi.org/10.1021/ac1031379" @default.
• W6267398 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3118260" @default.
• W6267398 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21294534" @default.
• W6267398 hasPublicationYear "2011" @default.
• W6267398 type Work @default.
• W6267398 sameAs 6267398 @default.
• W6267398 citedByCount "48" @default.
• W6267398 countsByYear W62673982012 @default.
• W6267398 countsByYear W62673982013 @default.
• W6267398 countsByYear W62673982014 @default.
• W6267398 countsByYear W62673982015 @default.
• W6267398 countsByYear W62673982016 @default.
• W6267398 countsByYear W62673982017 @default.
• W6267398 countsByYear W62673982018 @default.
• W6267398 countsByYear W62673982019 @default.
• W6267398 countsByYear W62673982022 @default.
• W6267398 countsByYear W62673982023 @default.
• W6267398 crossrefType "journal-article" @default.
• W6267398 hasAuthorship W6267398A5025419758 @default.
• W6267398 hasAuthorship W6267398A5026527210 @default.
• W6267398 hasAuthorship W6267398A5052226398 @default.
• W6267398 hasAuthorship W6267398A5062731220 @default.
• W6267398 hasAuthorship W6267398A5065884186 @default.
• W6267398 hasAuthorship W6267398A5077501113 @default.
• W6267398 hasBestOaLocation W62673982 @default.
• W6267398 hasConcept C116817701 @default.
• W6267398 hasConcept C119128265 @default.
• W6267398 hasConcept C162356407 @default.
• W6267398 hasConcept C179998833 @default.
• W6267398 hasConcept C185592680 @default.
• W6267398 hasConcept C2777463227 @default.
• W6267398 hasConcept C43617362 @default.
• W6267398 hasConceptScore W6267398C116817701 @default.
• W6267398 hasConceptScore W6267398C119128265 @default.
• W6267398 hasConceptScore W6267398C162356407 @default.
• W6267398 hasConceptScore W6267398C179998833 @default.
• W6267398 hasConceptScore W6267398C185592680 @default.
• W6267398 hasConceptScore W6267398C2777463227 @default.
• W6267398 hasConceptScore W6267398C43617362 @default.
• W6267398 hasIssue "5" @default.
• W6267398 hasLocation W62673981 @default.
• W6267398 hasLocation W62673982 @default.
• W6267398 hasLocation W62673983 @default.
• W6267398 hasLocation W62673984 @default.

• next