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• W627567 abstract "The subsolidus phase relations in the B-rich part of the ternary system, Na2O-SrO-B2O3, are investigated by the powder X-ray diffraction method. Four ternary compounds: NaSrBO3, NaSr4B3O9, Na3SrB5O10 and NaSrB5O9 were found in it, the two lasts are new. NaSrB5O9 crystallizes in the monoclinic space group P2(1)/c, with the lattice parameters a = 6.4963(1) angstrom, b = 13.9703(2) angstrom, c = 8.0515(l) angstrom, beta = 106.900(1)degrees. Na3SrB5O9 is also monoclinic, space group C2, a = 7.290(1) angstrom, b = 13.442(2) angstrom c = 9.792(1) angstrom, beta = 109.60(1). NaSrB5O9 is isostructural with another pentaborate NaCaB5O9, and its structure was refined by Rietveld method based on the structural model of NaCaB5O9. The fundamental building units are [B5O9](3-) anionic groups, forming complex thick anionic sheets, extending parallel to the ac plane. The Na and Sr atoms are all eight-coordinated with O atoms, forming trigonal dodecahedra. The [NaO8] polyhedra are distributed between the B-O sheets, while the [SrO8] polyhedra located in the sheets and connect with each other by edges to form infinite chains along the c-axis. (c) 2007 Elsevier Inc. All rights reserved." @default.
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• W627567 date "2007-04-01" @default.
• W627567 modified "2023-09-23" @default.
• W627567 title "The Na2O–SrO–B2O3 diagram in the B-rich part and the crystal structure of NaSrB5O9" @default.
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• W627567 doi "https://doi.org/10.1016/j.jssc.2007.02.014" @default.
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