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- W62767589 abstract "Abstract Hydroboration with diborane or borane generating reagents is a fast reaction leading to organoboranes, R3B, in essentially quantitative yields. Yet it suffers from certain disadvantages. Many of these difficulties can be overcome by use of substituted boranes with but one or two active B-H bonds. Among the reagents explored are dicyclohexylborane, disiamylborane, diisopinocampheylborane, catecholborane, dichloroboraneetherate, dichloroborane-methyl sulfide, dibromoborane-methyl sulfide, thexylchloroborane-methyl sulfide, thexylborane, isopinocampheylborane, monochloroborane etherate, monochioroborane-methyl sulfide, and monobromo-borane-methyl sulfide. These studies have revealed remarkable differences in selectivities. For example, it is now possible to hydroborate RCequivCR in the presence of RCequivCH, or vice versa. Similarly, it is possible to hydroborate RCHequalsCH2 in the presence of R(CH3)CequalsCH2, or vice versa. Indeed, one of the reagents reveals selectivities of cis alkenes over trans of Sub 100. These differences can often be utilized to advantage in complex syntheses." @default.
- W62767589 created "2016-06-24" @default.
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- W62767589 date "1983-01-01" @default.
- W62767589 modified "2023-09-27" @default.
- W62767589 title "NEW HYDROBORATING AGENTS" @default.
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- W62767589 doi "https://doi.org/10.1016/b978-0-08-029217-5.50026-7" @default.
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