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- W63556599 abstract "The performance of altervalent doped TiO2 catalysts under oxidative coupling of methane conditions is investigated. It is shown that higher-valence doping (W6+, Nb5+, Ta5+) of TiO2 enhances significantly methane conversion activity and reduces selectivity to nearly zero levels. On the other hand, doping TiO2 with lower valence cations (Li+, Zn+2) has a small influence on activity but results in a significant enhancement of selectivity. These results are attributed to alterations of the bulk electronic structure of the semiconductivity catalysts as well as to alterations of surface parameters such as acidity/basicity characteristics, oxygen ion mobility and lattice oxygen reactivity." @default.
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- W63556599 date "1993-01-01" @default.
- W63556599 modified "2023-10-16" @default.
- W63556599 title "Oxidative Coupling of Methane to C2 Hydrocarbons Over Doped Titania Catalysts" @default.
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- W63556599 doi "https://doi.org/10.1016/s0167-2991(08)64277-9" @default.
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