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- W63582364 abstract "The pyrolysis reaction of [Ru 3 (CO) 10 (dppe)], compound 1 , in toluene yields as the main product [Ru 4 (CO) 9 (μ-CO){μ 4 –η 2 -PCH 2 CH 2 P(C 6 H 5 ) 2 }(μ 4 –η 4 -C 6 H 4 )], compound 2 . The X-ray structure of 2 shows a benzyne group coordinated to a square of ruthenium atoms and a μ 4 –η 2 -PCH 2 CH 2 PPh 2 fragment. Variable-temperature NMR experiments showed three independent dynamic processes: a rotation of the benzyne group, CO migration and a twisting movement of the CH 2 CH 2 fragment. The thermolysis of [Ru 3 (CO) 10 (dfppe)], compound 3 , (dfppe=1,2-bis(dipentafluorophenylphosphino)ethane, carried out under the same conditions, showed 3 to be stable." @default.
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- W63582364 date "2002-10-01" @default.
- W63582364 modified "2023-10-18" @default.
- W63582364 title "Pyrolysis of [Ru3(CO)10(dppe)]: activation of CH and PPh bonds." @default.
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- W63582364 doi "https://doi.org/10.1016/s0022-328x(02)01817-x" @default.
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