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- W63792904 abstract "Ultra-thin films of the cofacially stacked phthalocyanine polymer, (A1PcF) n ' have been grown using the highly controlled technique of MBE. A parallel orientation of the polymer backbone to the substrate surface occurs in films on silicon and quartz, but epitaxy is not apparent. On single crystal alkalihalide substrates, the backbone is perpendicular to the substrate surface and an epitaxial relationship exists which is influenced by the electrophillic interaction between the substrate and phthalocyanine molecule. Especially, the ultra-thin films grown on the (100) surfaces of KCl or KBr single crystals show unusual spectroscopic properties which can be described by the possibility of pseudomorphic layer formation at the thin film/substrate interface. The existence of the layer (“defect”) is directly related to the degree of lattice mismatch and sterically enhanced interaction between the substrate and phthalocyanine." @default.
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- W63792904 date "1990-01-01" @default.
- W63792904 modified "2023-09-24" @default.
- W63792904 title "STRUCTURE AND PROPERTIES OF ULTRA-THIN ORGANIC FILMS PREPARED BY MBE METHOD" @default.
- W63792904 cites W2009522024 @default.
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- W63792904 doi "https://doi.org/10.1016/b978-0-444-88429-9.50105-1" @default.
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