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- W63839558 abstract "Five sulphonamides spanning a range of initial degrees of ionisation have been used as probes for the study of the mechanisms of electrophoretic mobility modification caused by increasing buffer concentrations (5–210 mM sodium phosphate) in capillary zone electrophoresis (CZE). Partition experiments at the CZE operational pH and a second pH where the analytes are uncharged permits independent determinations of the salt and temperature effects upon ionisation. At the CZE temperature, the underlying salt effects due to nonideal solute–solvent interactions are demonstrated. These are selective and indicate that the buffer concentration may be manipulated to facilitate resolution of analytes with differing degrees of ionisation. These selectivities are heightened by Joule heating. At elevated temperatures, the relative effects upon ionisation and viscosity were determined. These magnitudes were then combined and used in conjunction with the deviations in electrophoretic mobilities from the extrapolated behaviour of dilute buffers to estimate mean internal capillary temperatures." @default.
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- W63839558 date "1998-06-01" @default.
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- W63839558 title "Salt effects in capillary zone electrophoresis" @default.
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- W63839558 doi "https://doi.org/10.1016/s0021-9673(98)00189-7" @default.
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