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- W63841785 abstract "The electrochemical and spectroscopic (UV-Vis, EPR) properties of two series of dimeric cofacial porphyrins have been studied in aprotic media under an inert atmosphere, and in the presence of dioxygen. The existence of a “cofacial effect” created by the geometry of these dimers induces a new mechanistic pathway for the O2 fixation by the dicobalt derivatives, in which not only the electrons of the cobalt(II) but also those of the porphyrin rings are involved. Two kinds of complexes are obtained: a μ-superoxo and a μ-peroxo derivative. The availability of the electrons of the rings could be a clue to the comprehension of the mechanism by which these compounds promote the 4-electron reduction of dioxygen." @default.
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- W63841785 date "1991-01-01" @default.
- W63841785 modified "2023-09-25" @default.
- W63841785 title "Enhanced Electronic Delocalization in Face-to-Face Diporphyrins. Implication in the Unique Reactivity of the Cobalt Derivatives Towards Dioxygen and in the 4-Electron Reduction Mechanism of O2" @default.
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- W63841785 doi "https://doi.org/10.1016/s0167-2991(08)62838-4" @default.
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