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- W639435712 abstract "Reaction of Ni(NCS)2 with 4-(hydroxymethyl)pyridine leads to the formation of five new coordination compounds. The crystal structures of compounds 1-H2O, 1, 2 and 3 consist of discrete complexes, in which the Ni cations are coordinated by two terminal N-bonded thiocyanato anions and four neutral co-ligands, within slightly distorted octahedra. In the structure of 4, two Ni cations are linked into dimers by pairs of μ-1,3-bridging anions and are further connected into chains by the 4-(hydroxymethyl)pyridine ligand. Compound 4 shows an antiferromagnetic transition at TN = 6.7 K. The compounds were additionally characterized by IR spectroscopy, thermoanalytical methods and X-ray powder diffraction." @default.
- W639435712 created "2016-06-24" @default.
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- W639435712 date "2015-09-01" @default.
- W639435712 modified "2023-09-25" @default.
- W639435712 title "Synthesis, crystal structures and properties of Ni(NCS)2-4-(hydroxymethyl)pyridine coordination compounds" @default.
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- W639435712 doi "https://doi.org/10.1016/j.poly.2015.06.004" @default.
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