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- W641225815 abstract "A series of polybenzimidazoles containing sulfonyl groups were synthesized in Eaton's reagent for high temperature H2/CO2 separation membranes. The key monomer, 3,3′,4,4′-tetraaminodiphenylsulfone, was prepared via a novel and economical synthetic route starting from 4,4′-dichlorodiphenylsulfone. These polybenzimidazoles with sulfonyl moieties had enhanced solubilities in dipolar aprotic solvents relative to the commercial Celazole® that is prepared from diaminobenzidine. Thermal gravimetric analysis showed that the materials were stable at elevated temperatures with 5% weight loss values of at least 485 °C in either air or N2. Glass transition temperatures of three polybenzimidazoles in this series were ascertained by dynamic mechanical analysis to be 438–480 °C. These sulfonyl-containing polybenzimidazoles exhibited excellent gas separation properties for H2/CO2. Polymers from tetraaminodiphenylsulfone and either terephthalic or isophthalic acid crossed Robeson's upper bound for H2/CO2." @default.
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- W641225815 date "2015-08-01" @default.
- W641225815 modified "2023-10-15" @default.
- W641225815 title "Synthesis and characterization of polybenzimidazoles derived from tetraaminodiphenylsulfone for high temperature gas separation membranes" @default.
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- W641225815 doi "https://doi.org/10.1016/j.polymer.2015.06.021" @default.
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