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- W643857727 abstract "The aggregate structure of a nonionic trisiloxane surfactant at the liquid/solid interface was studied by Atomic Force Microscopy (AFM) as a function of substrate surface energy. The hydrophobicity of oxidized silicon wafer was gradually increased by increasing the amount of n-octadecyltrichlorosilane (OTS) monolayer coverage. AFM soft-contact imaging and force measurements captured the variation in surfactant aggregate structures from spherical micelles to elongated micelles, defected monolayer, and continuous monolayer with increasing surface hydrophobicity. The aggregate structural evolution at the solid/liquid interface resembles the microstructural sequence of the surfactant in bulk solution at room temperature. It is speculated that the hydrophobic attraction between the surfactant and the solid surface induces two-dimensional analogues of the surfactant bulk microstructures. The hydrophobic attraction affects the geometric packing parameter in a similar fashion as the increase in surfactant concentration." @default.
- W643857727 created "2016-06-24" @default.
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- W643857727 date "2003-08-17" @default.
- W643857727 modified "2023-10-17" @default.
- W643857727 title "Mesoscale Phenomena in Fluid Systems" @default.
- W643857727 doi "https://doi.org/10.1021/bk-2003-0861" @default.
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