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- W644691353 abstract "采用溶液聚合的方法，先合成了甲基丙烯酸缩水甘油酯（GMA）与甲基丙烯酸甲酯（MMA）的线型共聚物P（GMA—co—MMA）；然后通过环氧基团的开环成醚反应，将对羟基苯甲醛（HBA）键合于共聚物的侧链上，形成键合有苯甲醛（BA）的聚合物BA—P（GMA—co—MMA）；最后采用Adler方法，以BA—P（GMA—co—MMA）、苯甲醛及吡咯为反应物，在均相反应体系中，成功地实现了苯基卟啉（PP）在共聚物P（GMA—co-MMA）侧链的同步合成与键合，制得了卟啉功能化的线型大分子PP—P（GMA—co—MMA）．通过DTIR及^1H—NMR对功能大分子PP—P（GMA—co—MMA）的化学结构进行了表征，对其谱学性能进行了研究，较为深入地分析了其光物理行为．实验结果表明，大分子PP-P（GMA—co—MMA）具有与四苯基卟啉（TFP）相同的电子吸收光谱与荧光发射光谱．随着侧链上PP键合量的增大，大分子PP—P（GMA—co—MMA）的Soret与Q吸收带的峰强均不断增强，而Q发射带的强度则呈现先增大后有所减弱的规律，这是由大分子内的能量转移所致．" @default.
- W644691353 created "2016-06-24" @default.
- W644691353 creator A5050829718 @default.
- W644691353 creator A5070592637 @default.
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- W644691353 date "2009-01-01" @default.
- W644691353 modified "2023-09-25" @default.
- W644691353 title "Simultaneous Synthesis and Linkage of Porphyrin onto Side Chain of Copolymer P(GMA-<EM>co</EM>-MMA)" @default.
- W644691353 doi "https://doi.org/10.3866/pku.whxb20090225" @default.
- W644691353 hasPublicationYear "2009" @default.
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