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- W64585955 abstract "57Fe Mossbauer investigations are reported for K 0.3 Ba 0.7 Fe 2 S 3 and compared with the unsubstituted compound BaFe 2 S 3 in the temperature interval 4.2 < T < 293 K. According to the temperature dependence of the quadrupole splitting and the value of the centre shift (CS) both samples can be characterised as mixed valence compounds. A weakening in stiffness of the Fe sublattice follows from the decrease in Debye temperature (30 K), if Ba is substituted by K. The ordering temperature, determined from the appearance of a magnetic hyperfine split component, is roughly 40 K lower than the one for BaFe 2 S 3 indicating a strong influence of the interspersed cations on the magnetic exchange interaction." @default.
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- W64585955 date "2004-11-01" @default.
- W64585955 modified "2023-10-14" @default.
- W64585955 title "Mössbauer investigation of K0.3Ba0.7Fe2S3" @default.
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- W64585955 doi "https://doi.org/10.1016/j.jallcom.2004.04.022" @default.
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