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- W65180710 abstract "Sulfoxide, sulfinate and sulfonate are used as activators of acetylenic or vinyl units. Several a, β unsaturated synthons, namely acetylenic sulfoxide (1), vinyl sulfoxide (2), acetylenic sulfinate (3), acetylenic sulfonate (4), and l-propene-l, 3-sultone (5) are developed. Their applications in Diels-Alder reactions, heterocycle and alkaloid syntheses are also investigated. For the chiral acetylenic sulfoxide, the sulfoxide moiety not only enables chemical activation of the acetylene unit, it can also induce stereochemical control at the adjacent carbon centers to achieve enantioselective synthesis." @default.
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- W65180710 date "1997-01-01" @default.
- W65180710 modified "2023-09-27" @default.
- W65180710 title "Chiral acetylenic sulfoxides and related compounds in organic synthesis" @default.
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- W65180710 doi "https://doi.org/10.1007/bfb0119247" @default.
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