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• W652265849 abstract "Abstract Reactions of K2PtCl4 with TeRRʹ gave complexes of composition [PtCl2(TeRRʹ)2] (R/Rʹ = Ph2(1a), o-tol2 (1b), Mes2(1c), Ph/Mes (1d), o-tol/Mes (1e)). The complex [PtCl2(TeMes2)2] in refluxing THF afforded a mononuclear cyclometalated complex [PtCl{(CH2C6H2Me2-4,6)TeMes}(TeMes2)] (2). It tends to remain in equilibrium with a binuclear derivative [Pt(μ-Cl){(CH2C6H2Me2-4,6)TeMes}]2 (3) in CDCl3 solution. The complexes 1d and 1e did not undergo cyclometalation reaction under similar reaction conditions. The 2 on treatment with PPh3 gave [PtCl{(CH2C6H2Me2-4,6)TeMes}(PPh3)] (4). All the complexes have been characterized by elemental analysis and NMR (1H, 31P, 125Te, 195Pt) spectroscopy. Anagostic interactions have been recognised for facilitation of cyclometalation reactions. The molecular structures of trans-[PtCl2(TeMes2)2] (1c), trans-[PtCl2(PhTeMes)2] (1d), trans-[PtCl2(o-tolTeMes)2] (1e), [PtCl{(CH2C6H2Me2-4,6)TeMes}(TeMes2)] (2) and [PtCl{(CH2C6H2Me2-4,6)TeMes}(PPh3)] (4) have been established unambiguously by single crystal X-ray diffraction analyses." @default.
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• W652265849 date "2015-10-01" @default.
• W652265849 modified "2023-09-26" @default.
• W652265849 title "Role of anagostic interactions in cycloplatination of telluroethers: Synthesis and structural characterization" @default.
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• W652265849 doi "https://doi.org/10.1016/j.jorganchem.2015.05.062" @default.
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