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- W65239059 abstract "Zeolites with hydrophobic character, such as silicalites, were synthesized, and their structures studied by X-ray diffraction. Their potential use as adsorbents for the removal of organic molecules from water was investigated by series of experiments with aqueous solutions of lower alcohols. Adsorption isotherms of the Langmuir type were applied, and calculations showed that the amount of propanol adsorbed on silicalite corresponded to approximately 70% of the pore volume. The amounts of alcohols adsorbed per unit weight of zeolite decreased in the order n-propanol > ethanol > methanol, and the alcohol was more efficiently removed with silicalites than with other zeolites, such as ZSM5, AlPO 4 -zeolites and others, due to the more hydrophobic and less polar character of silicalite. F-silicalite, which contains small amounts of fluorine, also showed interesting properties, but had lower adsorption capacity than the regular silicalite. Adsorption experiments with aqueous acetone showed that silicalite had approximately the same adsorption capacity for acetone as for npropanol. Heats of adsorption were determined calorimetrically." @default.
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- W65239059 date "1985-01-01" @default.
- W65239059 modified "2023-09-25" @default.
- W65239059 title "Zeolites as Adsorbents for Alcohols from Aqueous Solutions" @default.
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- W65239059 doi "https://doi.org/10.1016/s0167-2991(08)65332-x" @default.
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