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- W65601831 abstract "Evidence is presented that the previously studied Prins and Friedel-Crafts-acetylation reactions of (+)-3-carene (IV) each involve electrophilic attack trans to the cyclopropyl ring to give the products I and IX, having the newly introduced C-4 substituents in an α-orientation. Through oxidation, I and IX were converted to a common intermediate, the ester VI. Analysis of the NMR spectra of the epimeric esters VI and VII and ketones IX and X with the aid of double decoupling techniques permitted assignment of the 4α and 4β configurations, respectively. Additional support for the assignments I and IX is provided by examination of the NMR spectra of the epoxides XII and XIII." @default.
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- W65601831 date "1968-01-01" @default.
- W65601831 modified "2023-10-14" @default.
- W65601831 title "Stereochemistry of electrophilic substitution of (+)-3-carene" @default.
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- W65601831 doi "https://doi.org/10.1016/0040-4020(68)88090-1" @default.
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