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- W656488947 abstract "A highly competitive system is the reaction at the three-phase boundary at which the electrode was exposed to both the oil and the water phase, explored by Scholz and coworkers. It is composed of an oil droplet mounted on the electrode in an aqueous solution. A typical cell apparatus is composed of the oil droplet including only a redox species, which is located on an electrode in an aqueous solution including supporting electrolyte, as is shown in Fig.1A. An air bubble mounted on an oil | water interface is a probe not only of interfacial tension but also of properties of three-phase boundary reactions. This report is devoted to investigating the static and dynamic behavior of the air bubble on the O|W interface in the context of the three-phase boundary reaction of ferrocene. The bubble kept spontaneously moving on the oil|water interface without applying any force, when it is less than 0.3 mm in diameter. The motion was irregular without decay, suggesting a contribution of Brownian motion. When the three-phase boundary reaction occurred, the bubble motion stopped. It was observed only in the potential domain at which ferrocene is oxidized. The force balance of the air bubble at the O|W interface will be formulated in terms of the interfacial tensions and the buoyancy. It will be demonstrated that the electrode reaction varies the surface tension at the O|W interface to cause surface convection." @default.
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- W656488947 date "2009-06-01" @default.
- W656488947 modified "2023-09-24" @default.
- W656488947 title "Driven motion of the third phase on the oil | water interface by three-phase boundary reactions" @default.
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