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- W658601932 abstract "チオアセトアミドと鉛およびカドミウムの反応による硫化物沈殿生成の反応速度を,温度75～85℃,過塩素酸酸性pH約3より0.4Mまでの水素イオン濃度のもとに測定した.その結果,沈殿反応のみかけの速度式Vp=kH+{H+}[CH3CSNH2]を得,反応は水素イオンにより自触的に進行することを明らかにした.85℃における水素イオン触媒係数は,kH+=1.7×10-1l/mol・minとなり,チオアセトアミドの加水分解による硫化水素発生反応のkH+にみかけ上一致する.反応中水素イオン濃度一定の条件で,所要の硫化鉛および硫化カドミウムの沈殿を得る反応条件が,硫化水素発生反応の速度式より求められる." @default.
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- W658601932 date "1961-01-01" @default.
- W658601932 modified "2023-09-25" @default.
- W658601932 title "Precipitation of lead and cadmium sulfides with thioacetamide from homogeneous solution" @default.
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- W658601932 doi "https://doi.org/10.2116/bunsekikagaku.10.585" @default.
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