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- W66090620 abstract "Herein the authors discuss scoping studies performed to develop an efficient way to prepare the Idaho National Engineering and Environmental Laboratory (INEEL) nominally high-level ({approximately}40 W/m{sup 3}) calcined radioactive waste (HLW) and liquid metal (sodium) reactor coolants for disposal. The investigated approach implements the chemistry of Hanford`s cancrinite-making clay reaction process via Oak Ridge National Laboratory`s (ORNL`s) formed-under-elevated-temperatures-and-pressures concrete monolith-making technology to make hydroceramics (HCs). The HCs differ from conventional Portland cement/blast furnace slag (PC/BFS) grouts in that the binder minerals formed during the curing process are hydrated alkali-aluminosilicates (feldspathoids-sodalites, cancrinites, and zeolites) rather than hydrated calcium silicates (CSH). This is desirable because (a) US defense-type radioactive wastes generally contain much more sodium and aluminum than calcium; (b) sodalites/cancrinites do a much better job of retaining the anionic components of real radioactive waste (e.g., nitrate) than do calcium silicates; (c) natural feldspathoids form from glasses (and therefore are more stable) in that region of the United States where a repository for this sort of waste could be sited; and (d) if eventually deemed necessary, feldspathoid-type concrete wasteforms could be hot-isostatically-pressed into even more durable materials without removing them from their original canisters." @default.
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- W66090620 date "1999-09-01" @default.
- W66090620 modified "2023-09-27" @default.
- W66090620 title "Preliminary formulation studies for a ``hydroceramic`` alternative waste form for INEEL HLW" @default.
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