FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W6644995> ?p ?o ?g. }

• W6644995 endingPage "428" @default.
• W6644995 startingPage "426" @default.
• W6644995 abstract "Interaction of palladium carboxylates [Pd(RCO 2 ) 2 ] n with acetone was studied and two new types of palladium polynuclear compounds containing acetonyl and carboxylate groups were isolated. The compounds of the first type are resented by Pd 4 (μ-CF 3 CO 2 ) 4 (μ, k 2 -CH 2 C(O)CH 3 ) 2 (η 3 -CH 2 C(OH)CH 2 ) 2 ·2CH 3 C(O)CH 3 . This complex has been characterized by the X-ray diffraction analysis. The compound has been shown to contain bridging enolate-anions and η 3 -coordinated 2-hydroxoallyl ligands. Both ligands represent the result of acetone transformations. The compound is the first transition metal complex simultaneously containing coordinated acetonyl and η 3 -coordinated 2-hydroxoallyl. The compounds of the second type represent polymeric complexes of the common formula [Pd 2 (μ-RCO 2 ) 2 (μ, k 2 -CH 2 C(O)CH 3 ) 2 ] n (R = CF 3 , CCl 3 ) containing only bridging enolate-anions. The obtained result shows that, in the presence of strong carboxylic acids, acetone acts as a high-reactive moiety towards palladium carboxylates. Interaction of palladium carboxylates [Pd(RCO 2 ) 2 ] n with acetone was studied and two new types of palladium polynuclear compounds containing acetonyl and carboxylate groups were obtained. The complex Pd 4 (μ-CF 3 CO 2 ) 4 (μ, k 2 -CH 2 C(O)CH 3 ) 2 (η 3 -CH 2 C(OH)CH 2 ) 2 was characterized by X-ray analysis and shown to contain η 3 -coordinated 2-hydroxoallyl ligand which is a result of acetone transformation. ►Palladium carboxylates [Pd(RCO 2 ) 2 ] n reveal high reactivity towards acetone. ►The reactivity depends on the presence of strong carboxylic acid. ►Acetone transforms into coordinated enolate-anions and hydroxoallyls. ►The first carboxylate-enolate platinum metal complex was characterized by X-ray analysis." @default.
• W6644995 created "2016-06-24" @default.
• W6644995 creator A5000977454 @default.
• W6644995 creator A5001079872 @default.
• W6644995 creator A5017138252 @default.
• W6644995 creator A5019490997 @default.
• W6644995 creator A5038659072 @default.
• W6644995 creator A5047674658 @default.
• W6644995 creator A5048773029 @default.
• W6644995 creator A5087779835 @default.
• W6644995 date "2011-02-01" @default.
• W6644995 modified "2023-10-18" @default.
• W6644995 title "Transformations of acetone in reactions with carboxylate complexes of palladium" @default.
• W6644995 cites W1532473706 @default.
• W6644995 cites W1968296833 @default.
• W6644995 cites W1970345335 @default.
• W6644995 cites W1973742633 @default.
• W6644995 cites W1979489398 @default.
• W6644995 cites W1988789709 @default.
• W6644995 cites W1989408167 @default.
• W6644995 cites W1990951828 @default.
• W6644995 cites W2011883651 @default.
• W6644995 cites W2015135543 @default.
• W6644995 cites W2023546325 @default.
• W6644995 cites W2032842297 @default.
• W6644995 cites W2049549760 @default.
• W6644995 cites W2050378314 @default.
• W6644995 cites W2056650671 @default.
• W6644995 cites W2058958937 @default.
• W6644995 cites W2074195862 @default.
• W6644995 cites W2085036067 @default.
• W6644995 cites W2087565617 @default.
• W6644995 cites W2093396230 @default.
• W6644995 cites W2116161724 @default.
• W6644995 cites W2141879927 @default.
• W6644995 cites W2313538235 @default.
• W6644995 cites W2331440286 @default.
• W6644995 cites W2953365195 @default.
• W6644995 doi "https://doi.org/10.1016/j.inoche.2010.12.018" @default.
• W6644995 hasPublicationYear "2011" @default.
• W6644995 type Work @default.
• W6644995 sameAs 6644995 @default.
• W6644995 citedByCount "6" @default.
• W6644995 countsByYear W66449952012 @default.
• W6644995 countsByYear W66449952013 @default.
• W6644995 countsByYear W66449952014 @default.
• W6644995 countsByYear W66449952015 @default.
• W6644995 countsByYear W66449952021 @default.
• W6644995 crossrefType "journal-article" @default.
• W6644995 hasAuthorship W6644995A5000977454 @default.
• W6644995 hasAuthorship W6644995A5001079872 @default.
• W6644995 hasAuthorship W6644995A5017138252 @default.
• W6644995 hasAuthorship W6644995A5019490997 @default.
• W6644995 hasAuthorship W6644995A5038659072 @default.
• W6644995 hasAuthorship W6644995A5047674658 @default.
• W6644995 hasAuthorship W6644995A5048773029 @default.
• W6644995 hasAuthorship W6644995A5087779835 @default.
• W6644995 hasConcept C116569031 @default.
• W6644995 hasConcept C155647269 @default.
• W6644995 hasConcept C161790260 @default.
• W6644995 hasConcept C170493617 @default.
• W6644995 hasConcept C178790620 @default.
• W6644995 hasConcept C185592680 @default.
• W6644995 hasConcept C2776568683 @default.
• W6644995 hasConcept C2778074193 @default.
• W6644995 hasConcept C2781213060 @default.
• W6644995 hasConcept C502130503 @default.
• W6644995 hasConcept C544153396 @default.
• W6644995 hasConcept C55493867 @default.
• W6644995 hasConcept C71240020 @default.
• W6644995 hasConceptScore W6644995C116569031 @default.
• W6644995 hasConceptScore W6644995C155647269 @default.
• W6644995 hasConceptScore W6644995C161790260 @default.
• W6644995 hasConceptScore W6644995C170493617 @default.
• W6644995 hasConceptScore W6644995C178790620 @default.
• W6644995 hasConceptScore W6644995C185592680 @default.
• W6644995 hasConceptScore W6644995C2776568683 @default.
• W6644995 hasConceptScore W6644995C2778074193 @default.
• W6644995 hasConceptScore W6644995C2781213060 @default.
• W6644995 hasConceptScore W6644995C502130503 @default.
• W6644995 hasConceptScore W6644995C544153396 @default.
• W6644995 hasConceptScore W6644995C55493867 @default.
• W6644995 hasConceptScore W6644995C71240020 @default.
• W6644995 hasIssue "2" @default.
• W6644995 hasLocation W66449951 @default.
• W6644995 hasOpenAccess W6644995 @default.
• W6644995 hasPrimaryLocation W66449951 @default.
• W6644995 hasRelatedWork W2012515522 @default.
• W6644995 hasRelatedWork W2026298973 @default.
• W6644995 hasRelatedWork W2047755775 @default.
• W6644995 hasRelatedWork W2058352133 @default.
• W6644995 hasRelatedWork W2062913516 @default.
• W6644995 hasRelatedWork W2090087135 @default.
• W6644995 hasRelatedWork W2332364304 @default.
• W6644995 hasRelatedWork W2949798790 @default.
• W6644995 hasRelatedWork W6644995 @default.
• W6644995 hasRelatedWork W874733353 @default.
• W6644995 hasVolume "14" @default.

• next