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- W6664148 abstract "Abstract The state of Mn and Fe ions in ion-exchanged or ion-supported zeolites and in physical mixtures of Mn and Fe salts (or oxides) with H− or Na− ZSM-5 zeolites is investigated by using ESR, XPS, TPDA and transformations of methanol and toluene. It is shown that a strong, solid-state interaction between the metal ions and the HZSM-5 zeolite takes place at elevated temperatures, in contrast to NaZSM-5. The metal ions are found to be homogeneously distributed within the zeolite structure after this interaction and exhibit properties of metal ions coordinated in the zeolite cationic sites. The introduction of metal ions into the zeolites, reflected also in the lower number of strong acid sites, is manifested in modified catalytic activity and selectivity of the zeolites." @default.
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- W6664148 date "1988-01-01" @default.
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- W6664148 title "Solid State Interactions of Mn or Fe Cations with ZSM-5 Zeolites" @default.
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- W6664148 doi "https://doi.org/10.1016/s0167-2991(09)60597-8" @default.
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