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- W6685449 abstract "Lightweight complex hydrides such as alkali or alkali-earth metal aluminohydrides, metal borohydrides, and metal amides or imides are attractive as hydrogen storage materials because of their large gravimetric hydrogen densities. Metal aluminohydrides, also known as alanates, have the formula M(AlH4)n, where AlH4 − is a tetrahedral ion. They contain 2.9–11.3 mass% of hydrogen. When alanates decompose on heating, hydrogen is released. The residual solid is M3AlH6+Al, MHn+Al, M+Al, or MxAly. Similarly, the BH4 − ion in lithium borohydride is also tetrahedral. Lithium borohydride contains 18.4 mass% of hydrogen. Modified lithium borohydrides desorb about 9 mass% of hydrogen on decomposition and are recharged to 7–9 mass% hydrogen capacity at a temperature of 873 K and pressure of 7 MPa. Metal amides or imides have the formula M(NH2)n or M2/n(NH), respectively, where the NH2 − and NH2− groups are the corresponding complex ions. When metal imides absorb hydrogen, they decompose into metal amides and hydrides. Composite systems with various combinations of metal amides and metal hydrides are designable for hydrogen storage. Their dehydrogenation reactions yield 3.5–7.4 mass% of hydrogen. Hence, these materials are promising for hydrogen storage." @default.
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- W6685449 date "2009-01-01" @default.
- W6685449 modified "2023-10-16" @default.
- W6685449 title "FUELS – HYDROGEN STORAGE | Complex Hydrides" @default.
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- W6685449 doi "https://doi.org/10.1016/b978-044452745-5.00066-6" @default.
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